中国出境旅游的外交效应

2000年以来，中国出境旅游高增长、高消费，影响力不断增大，成为国家外交战略的重要内容，外交效应逐渐显现。通过辨析中国出境旅游外交效应的概念、表现形式和结果，基于10个中国主要出境目的国的旅游互动数据，采用DIF-GMM计量经济模型，实证检验了中国出境旅游外交效应。结果表明，中国通过有序推进ADS协议、加强经济援助、举办“旅游年”活动、实施旅游“制裁”，并积极参与国际制度建设等旅游外交行为，促进了与世界各国的友好交往，维护了自身核心利益，提升了外交软实力和国际影响力。国际旅游反作用于国际关系，对国际关系具有显著的正向促进作用，不仅是国际关系的结果，而且是其重要动因之一。中国出境旅游与政治、经济、社会、文化等联动，多方面提升了中国的国际影响力。     

Hetaryl- and heteroarylvinyl-substituted nitrofurans identified as non-cytotoxic selective antitubercular agents

New (E)-5-[2-(5-nitrofuran-2-yl)vinyl]-1,2,4-oxadiazoles and 5-(5-nitrofuran-2-yl)-1,2,4-oxadiazoles were synthesized via the base-promoted condensation of nitrofuran-containing acyl chlorides with amidoximes. Testing these compounds against Gram-negative E. coli, Gram-positive B. subtilis and S. aureus as well as M. tuberculosis HRv37 strain revealed three compounds being selectively antimycobacterial. None of these compounds displayed any cytotoxicity towards human pancreatic epithelioid carcinoma cell line, PANC-1.     

The effect of amide solvent structure on the direct arylation polymerization (DArP) of 2‐Bromo‐3‐hexylthiophene

In this work, we investigate the influence of the amide solvent chemical structure on the properties of poly(3‐hexylthiophene) (P3HT) prepared via direct arylation polymerization (DArP). Our findings indicate that for successful polymerization the amide must possess an acyclic aliphatic structure since cyclization of an amide results in a complete shutdown of DArP reactivity as evidenced by failed polymerization in N‐methylpyrrolidone, whereas the presence of an aromatic motif renders the amide solvent susceptible to C? H activation and leads to incorporation of the solvent structure into the P3HT backbone, as demonstrated on the example of N,N‐diethylbenzamide. Additionally, we observed that the steric bulk of alkyl substituents on both the nitrogen atom and the carbonyl group within the amide structure has to be delicately balanced for optimal DArP reactivity. In the optimal cases, P3HT is obtained in high yield, with high molecular weight and contains a minimal amount of structural defects. The obtained polymer samples were comprehensively studied in terms of their chemical structure, optical, thermal and solid‐state properties in thin films using GPC analysis, ¹H NMR, MALDI, UV–vis, GIXRD spectroscopy, and DSC. We additionally note a drastic difference of the amide solvent effect between DArP and Stille polymerization. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2494–2500     

High‐order ADER‐WENO ALE schemes on unstructured triangular meshes—application of several node solvers to hydrodynamics and magnetohydrodynamics

In this paper, we present a class of high‐order accurate cell‐centered arbitrary Lagrangian–Eulerian (ALE) one‐step ADER weighted essentially non‐oscillatory (WENO) finite volume schemes for the solution of nonlinear hyperbolic conservation laws on two‐dimensional unstructured triangular meshes. High order of accuracy in space is achieved by a WENO reconstruction algorithm, while a local space–time Galerkin predictor allows the schemes to be high order accurate also in time by using an element‐local weak formulation of the governing PDE on moving meshes. The mesh motion can be computed by choosing among three different node solvers, which are for the first time compared with each other in this article: the node velocity may be obtained either (i) as an arithmetic average among the states surrounding the node, as suggested by Cheng and Shu, or (ii) as a solution of multiple one‐dimensional half‐Riemann problems around a vertex, as suggested by Maire, or (iii) by solving approximately a multidimensional Riemann problem around each vertex of the mesh using the genuinely multidimensional Harten–Lax–van Leer Riemann solver recently proposed by Balsara et al. Once the vertex velocity and thus the new node location have been determined by the node solver, the local mesh motion is then constructed by straight edges connecting the vertex positions at the old time level tⁿ with the new ones at the next time level t^{n + 1}. If necessary, a rezoning step can be introduced here to overcome mesh tangling or highly deformed elements. The final ALE finite volume scheme is based directly on a space–time conservation formulation of the governing PDE system, which therefore makes an additional remapping stage unnecessary, as the ALE fluxes already properly take into account the rezoned geometry. In this sense, our scheme falls into the category of direct ALE methods. Furthermore, the geometric conservation law is satisfied by the scheme by construction. We apply the high‐order algorithm presented in this paper to the Euler equations of compressible gas dynamics as well as to the ideal classical and relativistic magnetohydrodynamic equations. We show numerical convergence results up to fifth order of accuracy in space and time together with some classical numerical test problems for each hyperbolic system under consideration. Copyright © 2014 John Wiley & Sons, Ltd.     

Synthesis of conjugated polymers possessing diketopyrrolopyrrole units bearing phenyl,pyridyl, and thiazolyl groups by direct arylation polycondensation: Effects of aromatic groups in DPP on physical properties

Conjugated polymers containing phenyl‐, pyridyl‐, and thiazolyl‐flanked diketopyrrolopyrrole (DPP) were synthesized by direct arylation polycondensation of 3,4‐ethylenedioxythiophene derivatives and dibrominated DPP‐based monomers, in order to probe the effects of the aromatic groups in the DPP units on the absorption property, energy level, and crystallinity. A polymer possessing thiazolyl‐flanked DPP units was found to display long‐wavelength absorption properties and higher crystallinity than the polymers bearing phenyl‐ and pyridyl‐flanked DPP units. These features of the thiazolyl‐based polymer were afforded by its coplanar structure of the main chain. The synthesized polymers showed semiconducting properties in organic field effect transistors and organic photovoltaics. Direct arylation polycondensation is an efficient synthetic method that affords a series of DPP‐based polymers in a simple fashion and, thus, helping in a comprehensive understanding on the relationship between the aromatic groups in DPP units and their physical properties. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2337–2345     

Two‐Step direct arylation for synthesis of naphthalenediimide‐based conjugated polymer

A naphthalenediimide (NDI)‐based conjugated polymer was synthesized by a two‐step direct C‐H arylation sequence. In the first step, two ethylenedioxythiophene units were coupled to NDI by direct arylation. In the second step, the direct arylation polycondensation of the monomer, formed in the first step, with 2,7‐dibromo‐9,9‐dioctylfluorene afforded the corresponding NDI‐based conjugated polymer ( PEDOTNDIF ) with molecular weight of 21,500 in 91% yield. The optical and electrochemical properties of the polymer were evaluated. The polymer showed ambipolar behavior in organic field‐effect transistors (OFETs). The electron mobility of PEDOTNDIF was estimated to be 2.3 × 10^?6 cm² V^?1 s^?1 using an OFET device with source‐drain (S‐D) Au electrodes. A modified OFET device with S‐D MgAg electrodes increased the electron mobility for PEDOTNDIF to 1.0 × 10^?5 cm² V^?1 s^?1 due to the more suitable work function of these electrodes, which reduced the injection barrier to the semiconducting polymer. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1401–1407     

Diameter of a direct power of a finite group

We present two conjectures concerning the diameter of a direct power of a finite group. The first conjecture states that the diameter of Gⁿ with respect to each generating set is at most n(|G|?rank(G)); and the second one states that there exists a generating set 𝒜, of minimum size, for Gⁿ such that the diameter of Gⁿ with respect to 𝒜 is at most n(|G|?rank(G)). We will establish evidence for each of the above mentioned conjectures.     

Characterization of odorous contaminants in post‐consumer plastic packaging waste using multidimensional gas chromatographic separation coupled with olfactometric resolution

The increasing world population with their growing consumption of goods escalates the issue of sustainability concepts with increasing demands in recycling technologies. Recovery of post‐consumer packaging waste is a major topic in this respect. However, contamination with odorous constituents currently curtails the production of recycling products that meet the high expectations of both consumers and industry. To guarantee odor‐free recyclates, the main prerequisite is to characterize the molecular composition of the causative odorants in post‐consumer plastic packaging waste. However, targeted characterization of odorous trace contaminants among an abundance of volatiles is a major challenge and requires specialized and high‐resolution analytical approaches. For this aim, post‐consumer packaging waste was characterized by sensory analysis and two‐dimensional high resolution gas chromatography coupled with mass spectrometry and olfactometry. The 33 identified odorants represent various structural classes as well as a great diversity of smell impressions with some of the compounds being identified in plastics for the first time. Substances unraveled within this study provide insights into sources of odorous contamination that will require specific attention in the future in terms of screening and prevention in recycling products.     

3D Laser Micro‐ and Nanoprinting: Challenges for Chemistry

3D printing is a powerful emerging technology for the tailored fabrication of advanced functional materials. This Review summarizes the state‐of‐the art with regard to 3D laser micro‐ and nanoprinting and explores the chemical challenges limiting its full exploitation: from the development of advanced functional materials for applications in cell biology and electronics to the chemical barriers that need to be overcome to enable fast writing velocities with resolution below the diffraction limit. We further explore chemical means to enable direct laser writing of multiple materials in one resist by highly wavelength selective (λ‐orthogonal) photochemical processes. Finally, chemical processes to construct adaptive 3D written structures that are able to respond to external stimuli, such as light, heat, pH value, or specific molecules, are highlighted, and advanced concepts for degradable scaffolds are explored.     

Superconvergence of the direct discontinuous Galerkin method for convection‐diffusion equations

This paper is concerned with superconvergence properties of the direct discontinuous Galerkin (DDG) method for one‐dimensional linear convection‐diffusion equations. We prove, under some suitable choice of numerical fluxes and initial discretization, a 2k‐th and ‐th order superconvergence rate of the DDG approximation at nodes and Lobatto points, respectively, and a ‐th order of the derivative approximation at Gauss points, where k is the polynomial degree. Moreover, we also prove that the DDG solution is superconvergent with an order k + 2 to a particular projection of the exact solution. Numerical experiments are presented to validate the theoretical results. © 2016 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 33: 290–317, 2017